基于Pt/GQDs双掺杂的TiO2介孔复合材料制备及其光学与传感性能Preparation of Pt/GQDs doped TiO2 composite mesoporous materials for sensing application
吴涛,邵绍峰,饶伟锋
摘要(Abstract):
通过溶胶-凝胶法制备了Pt/GQDs双掺杂的TiO_2基挥发性有机化合物(VOCs)传感材料。利用紫外-可见光分光光度计(UV-Vis)、透射电子显微镜(TEM)、荧光光谱(PL)、X射线衍射仪(XRD)分别对Pt/GQDs-TiO_2复合材料进行分析和表征。GQDs的有效掺入,使Pt/GQDs-TiO_2复合材料对光的吸收从UV向更宽的可见光区域偏移,更有利于在室温条件下增强介孔材料对VOCs的传感。重点对Pt/GQDs-TiO_2复合材料进行了不同温度的焙烧处理,在室温情况下,检测了Pt/GQDs-TiO_2复合材料对不同VOCs气体的传感响应。结果表明,在焙烧温度为300℃时,Pt/GQDs-TiO_2复合材料在室温情况下对异丙醇表现出良好的传感特性,响应时间和恢复时间分别为15s和53s。
关键词(KeyWords): 铂;石墨烯量子点;二氧化钛;气体传感器;挥发性有机化合物;介孔材料
基金项目(Foundation): 国家自然科学基金资助(No.11474167);; NUIST人才引进基金资助(No.2241091301028)
作者(Author): 吴涛,邵绍峰,饶伟锋
DOI: 10.14106/j.cnki.1001-2028.2017.03.010
参考文献(References):
- [1]ZHANG J,LIU X H,NERI G,et al.Nanostructured materials for room-temperature gas sensors[J].Adv Mater,2016,28:795-831.
- [2]VIJAYALAKSHMI K,KARTHICK K,TAMILARASAN K.Enhanced H2 sensing properties of a-plane Zn O prepared on c-cut sapphire substrate by sputtering[J].Mater Electron,2013,24:1325-1331.
- [3]INYAWILERTA K,WISITSORA-ATB A,TUANTRANONTB A,et al.Ultra-rapid VOCs sensors based on sparked-In2O3sensin g materials[J].Sens Actuat B,2014,192:745-754.
- [4]PARK S,SUN G J,KHEEL H,et al.Hydrogen gas sensing of Co3O4-decorated WO3 nanowires[J].Met Mater Int,2016,22:156-162.
- [5]REN H B,ZHAO W,WANG L Y,et al.Preparation of porous flower-like Sn O2 micro/nano structures and their enhanced gas sensing property[J].J Alloys Compd,2015,653:611-618.
- [6]GE S,ZHENG H X,SUN Y F,et al.Ag/Sn O2/graphene ternary nanocomposites and their sensing properties to volatile organic compounds[J].J Alloys Compd,2015,659:127-131.
- [7]BAVYKIN D V,FRIEDRICH J M,WALSH F C.Protonated titanates and Ti O2 nanostructured materials:synthesis,properties and applications[J].Adv Mater,2006,18:2807-2824.
- [8]LAW M,GREENE L E,JOHNSON J C,et al.Nanowire dye-sensitized solar cells[J].Nat Mater,2005,4:455-459.
- [9]BURNSIDE S D,SHKLOVER V,BARBE C,et al.Selforganization of Ti O2 nanoparticles in thin films[J].Chem Mater,1998,10:2419-2425.
- [10]HU P Q,DU G J,ZHOU W J,et al.Enhancement of ethanol vapor sensing of Ti O2 nanobelts by surface engineering[J].Appl Mater Interfaces,2010,2:3263-3269.
- [11]LIU B,AYDIL E S.Growth of oriented single-crystalline rutile Ti O2 nanorods on transparent conducting substrates for dye-sensitized solar cells[J].J Am Chem Soc,2009,131:3985-3990.
- [12]YANG H G,LIU G,QIAO S Z,et al.Solvothermal synthesis and photoreactivity of anatase Ti O2 nanosheets with dominant{001}facets[J].J Am Chem Soc,2009,131:4078-4083.
- [13]MOR G K,SHANKAR K,PAULOSE M,et al.Use of highly-ordered Ti O2 nanotube arrays in dye-sensitized solar cells[J].Nano Lett,2006,6:215-218.
- [14]ZURUZI A S,MACDONALD N C.Facile fabrication and integration of patterned nanostructured Ti O2 for microsystems applications[J].Adv Funct Mater,2005,15:396-402.
- [15]HAZRA A,BHOWMIK B,DUTTA K,et al.Stoichiometry,length,and wall thickness optimization of Ti O2 nanotube array for efficient alcohol sensing[J].ACS Appl Mater Interfaces,2015,7:9336-9348.
- [16]GASPERA1 E D,MURA A,MENIN E,et al.Reducing gases and VOCs optical sensing using surface plasmon spectroscopy of porous Ti O2-Au colloidal films[J].Sens Actuat B,2013,187:363-370.
- [17]?ENNIK E,ALEV O,?ZTüRK Z Z.The effect of Pd on the H2 and VOC sensing properties of Ti O2 nanorods[J].Sens Actuat B,2016,229:692-700.
- [18]RYU J,LEE E,LEE S,et al.Fabrication of graphene quantum dot-decorated graphene sheets via chemical surface modification[J].Chem Commun,2014,50:15616-15618.
- [19]GUPTA B K,KEDAWAT G,AGRAWAL Y,et al.A novel strategy to enhance ultraviolet light driven photocatalysis from graphene quantum dots infilled Ti O2 nanotube arrays[J].RSC Adv,2015,5:10623-10631.
- [20]FENG L,TANG X Y,ZHONG Y X,et al.Ultra-bright alkylated graphene quantum dots[J].Nanoscale,2014,6:12635-12643.
- [21]QU D,ZHENG M,DU P,et al.Highly luminescent S,N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts[J].Nanoscale,2013,5:12272-12277.
- [22]PAN D,XI C,LI Z,et al.Electrophoretic fabrication of highly robust,efficient,and benign hetero-junction photoelectrocatalysts based on graphene-quantum-dot sensitized Ti O2 nanotube arrays[J].J Mater Chem A,2013,1:3551-3555.
- [23]PAN D,ZHANG J,LI Z,et al.Hydrothermal route for cutting graphene sheets into blue-luminescent graphene quantum dots[J].Adv Mater,2010,22:734-737.
- [24]XUE Q,HUANG H,WANG L,et al.Nearly monodisperse graphene quantum dots fabricated by amine-assisted cutting and ultrafiltration[J].Nanoscale,2013,5:12098-12103.
- [25]LI Y,HU Y,ZHAO Y,et al.An electrochemical avenue to green-luminescent graphene quantum dots as potential electron-acceptors for hotovoltaics[J].Adv Mater,2011,23:776-780.
- [26]TANG L,JI R,LI X,et al.Deep ultraviolet to near-infrared emission and photoresponse in layered N-doped graphene quantum dots[J].ACS Nano,2014,8:6312-6320.
- [27]GE J,LAN M,ZHOU B,et al.A graphene quantum dot photodynamic therapy agent with high singlet oxygen generation[J].Nat Commun,2014,5:4596-4604.
- [28]YE R,XIANG C,LIN J,et al.Coal as an abundant source of graphene quantum dots[J].Nat Commun,2013,4:2943-2949.
- [29]WANG L,WANG Y,XU T,et al.Gram-scale synthesis of sin gle-crystalline grapheme quantum dots with superior optical properties[J].Nat Commun,2014,5:5357-5366.
- [30]NURUNNABI M,KHATUN Z,HUH K M,et al.In vivo biodistribution and toxicology of carboxylated graphene quantum dots[J].ACS Nano,2013,7:6858-6867.
- [31]CHONG Y,MA Y,SHEN H,et al.The in vitro and in vivo toxicity of graphene quantum dots[J].Biomaterials,2014,35:5041-5048.
- [32]SHEN P,XIA Y.Synthesis-modification integration:one-step fabrication of boronic acid functionalized carbon dots for fluorescent blood sugar sensing[J].Anal Chem,2014,86:5323-5329.
- [33]KWON W,KIM Y H,LEE C L,et al.Electroluminescence from graphene quantum dots prepared by amidative cutting of tattered graphite[J].Nano Lett,2014,14:1306-1311.
- [34]ZHU H H,LIU A,XU Y H,et al.Graphene quantum dots directly generated from graphite via magnetron sputtering and the application in thin-film transistors[J].Carbon,2015,88:225-232.
- [35]WANG Z F,ZENG H,SUN L.Graphene quantum dots:versatile photoluminescence for energy,biomedical,and environmental applications[J].J Mater Chem C,2015,3:1157-1165.
- [36]YUAN F,DING L,LI Y,et al.Multicolor fluorescent graphene quantum dots colorimetrically responsive to all-p H and a wide temperature range[J].Nanoscale,2015,7:11727-11733.
- [37]LIU Y S,GAO B,QIAO Z Q,et al.Gram-scale synthesis of graphene quantum dots from single carbon atoms growth via energetic material deflagration[J].Chem Mater,2015,27:4319-4327.
- [38]YEH T F,CHEN S J,TENG H S.Syner gistic effect of oxygen and nitrogen functionalities for graphene-based quantum dots used in photocatalytic H2 production from water decomposition[J].Nano Energy,2015,12:476-485.
- [39]DELUCA L,DONATO A,SANTANGELO S,et al.Hydrogen sensing characteristics of Pt/Ti O2/MWCNTs composites[J].Int J Hydrogen Energy,2012,37:1842-1851.
- [40]GHASEMPOUR R,MORTAZAVI S Z,IRAJIZAD A,et al.Hydrogen sensing properties of multi-walled carbon nanotube films sputtered by Pd[J].Int J Hydrogen Energy,2010,35:4445-4449.
- [41]ESFANDIAR A,GHASEMI S,IRAJIZAD A,et al.The decoration of Ti O2/reduced graphene oxide by Pd and Pt nanoparticles for hydrogen gas sensing[J].Int J Hydrogen Energy,2012,37(20):15423-15432.
- [42]ZHANG Y H,TANG Z R,FU X Z,et al.Ti O2 graphene nanocomposites for gas-phase photocatalytic degradation of volatile aromatic pollutant:is Ti O2 graphene truly different from other Ti O2 carbon composite materials[J].ACS Nano,2010,4(12):7303-7314.
- [43]DRBOHLAVOVA J,VOROZHTSOVA M,HRDY R,et al.Self-ordered Ti O2 quantum dot array prepared via anodic oxidation[J].Nanoscale Res Lett,2012,7(1):123.
- [44]ABAZOVIC N D,COMOR M I,DRAMICANIN M D,et al.Photoluminescence of anatase and rutile Ti O2 particles[J].J Phys Chem B,2006,110:25366-25370.